Written answers

Wednesday, 16 October 2013

Department of Health

Water Fluoridation

Photo of Maureen O'SullivanMaureen O'Sullivan (Dublin Central, Independent)
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127. To ask the Minister for Health if he will explain the discrepancy of the CAS number of natural fluoride being 16984-48-8 while the product specification of fluoride used in our water is different 16961-83-4 (details supplied); the reason natural fluoride is not being used in our water supply; the organisation that has approved the fluoride as detailed in the product specification as being fit for human consumption; and if he will make a statement on the matter. [43734/13]

Photo of Alex WhiteAlex White (Dublin South, Labour)
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Fluorine is one of the most chemically reactive elements in nature. As a consequence, it is always found in combination with other elements. CAS number 16984-48-8 relates to the fluoride ion. Fluoride compounds have different CAS numbers, e.g.16961-83-4 for Hydrofluosilicic Acid (HFSA), which is used for water fluoridation. The fluoride currently used for water fluoridation is sourced as a primary product. It is mined directly from a raw material source, the mineral fluorospar as calcium fluoride (CaF2). It then goes through a purification process to conform to tightly controlled specifications under the requirements of CEN Standard I.S.EN 12175:2001 to produce HFSA. It should also be noted that there are fluoridated public water supplies where there are existing background levels of naturally occurring fluoride and these levels are augmented using HFSA to the prescribed optimal level.

The principles for approval of use of HFSA in treatment of water intended for human consumption are no different to those relating to other chemicals used in drinking water treatment, such as disinfectants and coagulants. No water treatment chemical is intended for direct human consumption. The level of fluoride in drinking water in Ireland has been set at between 0.6-0.8 parts per million. This level of fluoride is deemed optimal for protecting the oral health of all age groups.

Comments

Anna Felton
Posted on 23 Apr 2014 9:08 pm (Report this comment)

If the fluoride is sourced as Calcium fluoride from fluorspar at what point does it change to Hydrofluorosilicic acid?

It seems strange that the purification process would add these elements (according to Chemifloc's page on HFSA)

Hydrofluorosilicic Acid (10.9%)
Arsenic (As)

Anna Felton
Posted on 23 Apr 2014 9:09 pm (Report this comment)

Ah sorry - most of my post didn't appear. I'm wondering is there a limit to characters as in Twitter?

Anna Felton
Posted on 23 Apr 2014 9:11 pm (Report this comment)

So I'll just post the link to Chemifloc's page on HFSA
http://www.chemifloc.com/specsheets/HydrofluosilicicAcid11pc...
Thanks in advance. Anna Felton

Anna Felton
Posted on 2 Oct 2014 8:33 pm (Report this comment)

Could I please have a response to my query about at what point in the process the mined Calcium fluoride becomes Hydrofluorosilicic acid and what process is used to achieve this? Thanks. Anna Felton

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